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LIVERMORIUM

30th July, 2024

LIVERMORIUM

Source: NEWS9LIVE

Disclaimer: Copyright infringement not intended.

Context

  • Scientists at Berkeley Lab created livermorium (element 116) using titanium-50, marking a step toward synthesizing element 120.
  • The process involved a 22-day experiment using a powerful particle accelerator to fuse titanium-50 with a plutonium target, producing two atoms of livermorium.
  • The discovery is significant for studying the stability and properties of superheavy elements. Future efforts will target the creation of element 120, potentially offering new insights into atomic nuclei.

 Details

What is Element 116 (Livermorium) and Why Does It Matter?

  • Superheavy Elements: Livermorium belongs to the "superheavy" category of elements, which exist beyond the known elements in the periodic table and are typically very unstable.
  • Significance: The creation of livermorium demonstrates a new method that could be used to create even heavier elements, such as element 120, providing valuable insights into the behavior of atoms at their heaviest.

How Was Element 116 Created?

  • Particle Accelerator: The Berkeley Lab team used a powerful particle accelerator to smash together titanium-50 atoms.
  • Method: Researchers combined isotopes of titanium and plutonium to create livermorium.
  • Achievement: Over 22 days, they managed to create two atoms of livermorium, marking a significant accomplishment.

Creating Heavier Atoms

  • Isotopes: Titanium-50 was chosen for its specific number of protons and neutrons. Previous superheavy elements were made using a different isotope, calcium-48, known for its favorable properties for fusion.
  • Beam Production: The process involved heating titanium metal to nearly 3000 degrees Fahrenheit and using advanced equipment to produce and accelerate the beam.

Why Target Element 120?

  • Goal: The ultimate aim is to create element 120, the heaviest element ever made, which would occupy the eighth row of the periodic table.
  • Potential Discoveries: Element 120 could reveal new properties about atomic nuclei, possibly leading to the discovery of more stable superheavy elements.

Livermorium

  • Livermorium is a synthetic element with the atomic number 116 and symbol Lv.
  • It was first synthesized in 2000 through a collaboration between the Joint Institute for Nuclear Research (JINR) in Dubna, Russia, and the Lawrence Livermore National Laboratory (LLNL) in the United States.
  • The element is named in honor of LLNL and the city of Livermore, California.
  • Discovery and Synthesis:Livermorium was produced by bombarding curium-248 atoms with calcium-48 ions, resulting in the creation of a single atom of livermorium.

Properties

  • Physical Properties:
      • State at Room Temperature:Predicted to be solid.
      • Density:Estimated to be around 12.9 g/cm³.
      • Melting Point:Predicted between 637–780 K.
      • Boiling Point:Predicted between 1035–1135 K.
      • Appearance:Not yet observed in sufficient quantities to confirm visual characteristics​​.
  • Chemical Properties:
      • Oxidation States:Predicted to be -2, +2, and +4.
      • Reactivity:Expected to exhibit some similarities with other group 16 elements, like polonium. However, its exact chemical behavior remains largely unexplored due to its instability and the challenges of studying such heavy elements​​.
  • Isotopes:
      • The known isotopes of livermorium range from ^290Lv to ^293Lv. The most stable isotope, ^293Lv, has a half-life of about 60 milliseconds, making it one of the more stable superheavy elements. This relative stability places livermorium near the so-called "island of stability" in the periodic table​​.

Titanium

Attribute

Details

Chemical Symbol

Ti

Atomic Number

22

Atomic Weight

47.867

Density

4.506 g/cm³ at room temperature

Appearance

Silvery grey-white metallic

Melting Point

1941 K

Boiling Point

3560 K

Crystal Structure

Hexagonal Close Packed

Magnetic Properties

Nonmagnetic, paramagnetic in a magnetic field

Oxidation States

+2, +3, +4

Key Properties

High strength-to-density ratio, corrosion resistance, low thermal expansion, biocompatibility

Primary Uses

Aerospace (aircraft structures, engines), medical implants (prosthetics, dental implants), industrial (chemical processing, desalination), sports equipment (golf clubs, bicycles), pigments and additives (titanium dioxide in paints, plastics, paper)

Discovery

First identified in 1791 by William Gregor; named by Martin Heinrich Klaproth in 1795

Historical Significance

Initially difficult to isolate, significant industrial use began in the 20th century

Synthetic Elements In The Periodic Table

Element

Symbol

Atomic Number

Discovery Year

Half-life

Method of Synthesis

Notable Uses/Properties

Technetium

Tc

43

1937

6 hours to 4.2 million years

Neutron capture and decay

Radiopharmaceuticals, corrosion-resistant alloys

Promethium

Pm

61

1945

17.7 years

Fission products from uranium and thorium

Nuclear batteries, research

Neptunium

Np

93

1940

2.14 million years

Neutron bombardment of uranium-238

Research, nuclear reactors

Plutonium

Pu

94

1940

24,110 years

Neutron capture in uranium-238

Nuclear weapons, nuclear reactors

Americium

Am

95

1944

432.2 years

Neutron bombardment of plutonium

Smoke detectors, radiography

Curium

Cm

96

1944

15.6 million years

Neutron bombardment of plutonium

Research, alpha-particle sources

Berkelium

Bk

97

1949

330 days

Neutron bombardment of americium

Research

Californium

Cf

98

1950

2.6 years

Neutron bombardment of curium

Neutron sources, cancer treatment

Einsteinium

Es

99

1952

1.3 years

Thermonuclear explosion debris

Research

Fermium

Fm

100

1952

100.5 days

Thermonuclear explosion debris

Research

Mendelevium

Md

101

1955

28 days

Alpha particle bombardment of einsteinium

Research

Nobelium

No

102

1966

58 minutes

Bombardment of californium with carbon ions

Research

Lawrencium

Lr

103

1961

3.6 hours

Bombardment of californium with boron ions

Research

Rutherfordium

Rf

104

1964

1.3 hours

Bombardment of curium with carbon ions

Research

Dubnium

Db

105

1967

34 seconds

Bombardment of californium with nitrogen

Research

Seaborgium

Sg

106

1974

2.4 minutes

Bombardment of californium with oxygen

Research

Bohrium

Bh

107

1981

61 seconds

Bombardment of bismuth with chromium

Research

Hassium

Hs

108

1984

16 seconds

Bombardment of lead with iron

Research

Meitnerium

Mt

109

1982

7.6 seconds

Bombardment of bismuth with iron

Research

Darmstadtium

Ds

110

1994

10 seconds

Bombardment of lead with nickel

Research

Roentgenium

Rg

111

1994

26 seconds

Bombardment of bismuth with nickel

Research

Copernicium

Cn

112

1996

29 seconds

Bombardment of lead with zinc

Research

Nihonium

Nh

113

2004

20 seconds

Bombardment of bismuth with zinc

Research

Flerovium

Fl

114

1998

2.7 seconds

Bombardment of plutonium with calcium

Research

Moscovium

Mc

115

2003

0.7 seconds

Bombardment of americium with calcium

Research

Livermorium

Lv

116

2000

0.6 seconds

Bombardment of curium with calcium

Research

Tennessine

Ts

117

2010

78 milliseconds

Bombardment of berkelium with calcium

Research

Oganesson

Og

118

2002

0.9 milliseconds

Bombardment of californium with calcium

Research

 Periodic Table

Aspect

Description

History and Development

  • The Periodic Table was first conceptualized by Dmitri Mendeleev in 1869, who arranged elements by increasing atomic mass and observed periodic patterns in their properties.
  • This early table left gaps for undiscovered elements, which Mendeleev predicted with remarkable accuracy.
  • The modern Periodic Table is arranged by increasing atomic number, a refinement introduced by Henry Moseley, which resolved inconsistencies in Mendeleev's arrangement.

Structure

  • The Periodic Table consists of 7 rows called periods and 18 columns called groups or families.
  • Elements are arranged in order of increasing atomic number (number of protons).
  • Each period corresponds to the number of electron shells an element's atoms possess, while each group shares the same number of electrons in their outermost shell, leading to similar chemical behaviors.

Major Categories

  • Metals: Located on the left and center, characterized by high electrical conductivity, malleability, ductility, and a lustrous appearance.
  • Nonmetals: Located on the right side, they are generally poor conductors of heat and electricity and can be gases, liquids, or solids at room temperature.
  • Metalloids: Found along the zigzag line (stair-step) between metals and nonmetals, these elements exhibit properties intermediate between those of metals and nonmetals.

Periodic Trends

  • Atomic Radius: Decreases across a period due to increasing nuclear charge pulling electrons closer to the nucleus, increases down a group as additional electron shells are added.
  • Ionization Energy: The energy required to remove an electron from an atom; it increases across a period due to stronger nuclear attraction, decreases down a group as electrons are farther from the nucleus.
  • Electron Affinity: The energy change when an electron is added to a neutral atom; generally becomes more negative across a period, indicating a greater tendency to accept electrons.

Notable Groups

  • Alkali Metals (Group 1): Highly reactive, especially with water, producing hydrogen gas and a strong base. Examples include lithium (Li), sodium (Na), and potassium (K).
  • Alkaline Earth Metals (Group 2): Less reactive than alkali metals but still form basic oxides. Examples include magnesium (Mg) and calcium (Ca).
  • Transition Metals (Groups 3-12): Known for their ability to form various oxidation states and colorful compounds. Includes elements like iron (Fe), copper (Cu), and gold (Au).
  • Halogens (Group 17): Very reactive nonmetals, especially with alkali and alkaline earth metals to form salts. Examples include fluorine (F), chlorine (Cl), and iodine (I).
  • Noble Gases (Group 18): Inert gases with full valence electron shells, making them very stable and unreactive. Includes helium (He), neon (Ne), and argon (Ar).

Block Classification

Elements are divided into blocks based on their electron configurations:

  • s-block: Groups 1 and 2 (and Helium).
  • p-block: Groups 13 to 18.
  • d-block: Transition metals, characterized by d-orbital filling.
  • f-block: Lanthanides and actinides, known as inner transition metals, characterized by f-orbital filling.

Applications and Uses

The elements of the periodic table have diverse applications in various fields:

  • Metals like iron and aluminum are used in construction and manufacturing.
  • Nonmetals like oxygen are essential for life, while carbon is the basis of organic chemistry.
  • Metalloids like silicon are crucial in electronics and semiconductors [7][8].

Modern Discoveries

The discovery of new elements continues, with recent additions including superheavy elements like nihonium (Nh, atomic number 113), moscovium (Mc, 115), tennessine (Ts, 117), and oganesson (Og, 118). These elements are synthesized in laboratories and often have very short half-lives, existing only for fractions of a second.

Sources:

NEWS9LIVE

PRACTICE QUESTION

Q: Consider the following statements regarding the properties of elements in the periodic table:

  1. The atomic radius generally increases from left to right across a period.
  2. Ionization energy generally decreases down a group in the periodic table.
  3. Electronegativity values generally increase from left to right across a period.

Which of the statements given above is/are correct?

  1. a) 1 and 2 only
    b) 2 and 3 only
    c) 1 and 3 only
    d) 1, 2, and 3

Answer: b)